See the couple's relationship unfold...
Brad has been married to Friends star Jennifer Aniston since 2000 but is rumoured to be getting close to Angelina during filming.
Three months after Brad and Jennifer’s divorce is finalised, he and Angelina are first seen together in public as a couple in April 2005.
Angelina insists Brad didn’t cheat on Jen but later admits that they fell in love while shooting the flick.
Things become serious between Angelina and Brad pretty quickly.
Angelina is already mum to son Maddox, who she adopted from Cambodia in March 2002. She adopts six-month-old daughter Zahara from Ethiopia in July 2005.
In January 2006, Brad legally adopts both of Angelina’s children and their names are changed to Maddox Jolie-Pitt and Zahara Jolie-Pitt.
That month, Angelina confirms she’s pregnant. She and Brad welcome their little girl Shiloh in May 2006. Shiloh becomes the first baby to have a wax figure of herself in Madame Tussauds, New York.
In March 2007, Brad and Angelina adopt three-year-old Pax from Vietnam.
The couple are clearly keen to expand their brood even further as it’s announced that Angelina is pregnant again in February 2008. She later reveals that they’re expecting twins.
Angelina gives birth to Knox and Vivienne at the Lenval Hospital in Nice, France in July 2008.
Despite having settled into family life, Brad and Angelina continue to hit the headlines with stories about their controversial relationship.
It’s rumoured that their romance is ‘under strain’. However, in July 2010 Angelina gets a tattoo on her inner thigh in honour of Brad.
After a seven-year relationship, Brad finally proposes to Angelina in April 2012.
Two years later in August 2014, they tie the knot in France.
Read on to check out what else Angelina and Brad have faced throughout their relationship…